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acetone oxime : ウィキペディア英語版
acetone oxime

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Acetone oxime (acetoxime) is the organic compound with the formula (CH3)2CNOH. It is the simplest example of a ketoxime. It is a white crystalline solid that is soluble in water, ethanol, ether, chloroform, and ligroin. It is used as a reagent in the synthesis of more complex organic compounds.〔Steven M. Weinreb, Kristina Borstnik "Acetone Oxime" e-EROS Encyclopedia of Reagents for Organic Synthesis, 2007. 〕
== Preparation ==
Acetone oxime is synthesized by the condensation of acetone and hydroxylamine in the presence of HCl:〔Handbook of Chemistry and Physics (【引用サイトリンク】url=http://www.hbcpnetbase.com/ )〕〔
:(CH3)2CO + H2NOH → (CH3)2CNOH + H2O
It can also be generated via ammoxidation of acetone in the presence of hydrogen peroxide.〔Xinhua Liang, Zhentao Mi, Yaquan Wang, Li Wang, Xiangwen Zhang "Synthesis of acetone oxime through acetone ammoximation over TS-1" Reaction Kinetics and Catalysis Letters Volume 82, pp 333-337. ().〕

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